
Photo courtesy of Pacific Regional Soil Science Society.
A trace element is an element whose concentration is less than 1000 ppm (0.1%) in a sample (rock, soil, or any natural product). Trace elements include:
-
Trace Metals
(definition) -
Heavy Metals
(definition) -
Mincronutrients
(definition)
The main sources of trace elements are soil parent materials (rocks), fertilizers, biosolids, irrigation water, coal combustion residues, auto emissions, and metal-smelting industries. Even though some trace elements originate from rocks and some are essential for plant growth and development, when present in soils at elevated levels those same elements become toxic. Trace elements that have been taken up by plants, especially those grown on contaminated soils, could move up the food chain, some accumulating in the fatty tissue of animals and/or humans.
Some trace elements of potential concern as soil contaminants are: arsenic (As), boron (B), cadmium (Cd), chromium (Cr), copper (Cu), fluorine (F), lead (Pb), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), selenium (Se), and zinc (Zn).
Use this diagram to navigate to each section by clicking on each box:
TRACE ELEMENTS
Sampling
Sample Preparation
Total Trace Element
- HF digestion
- Aqua regia and other acid digestions
Extractable Metals
- Neutral salts
- Chelating agents (EDTA, DPTA)
Speciation or Sequential Extractions
Instrumentation & Measurement
- Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES)
- Atomic Absorption Spectrophotometry (AAS)
Occurrence and significance of some trace elements
| Element | Source | Effects and significance |
| Arsenic | Mining by-product, pesticides, chemical waste | Toxic, possibly carcinogenic |
| Cadmium | Industrial discharge, mining waste, metal planting, water pipes | Toxic to aquatic biota. Causes kidney damage, destroys red blood cells |
| Chromium | Metal planting, cooling-tower water additive | Possibly carcinogenic as Cr(VI) |
| Lead | Industry, mining, plumbing, coal, gasoline | Toxic (anemia, kidney disease, nervous system) |
| Copper | Metal planting, industrial and domestic wastes, mining, mineral leaching | Micronutrient, toxic to plants at moderate levels |
| Zinc | Industrial waste, metal planting, plumbing | Micronutrient in many metalloenzymes, but toxic to plants at higher levels. Major component of sewage sludge |
References and Resources:
- Carter, M.R., and E.G. Gregorich (eds). 2008. Soil sampling and methods of analysis. 2nd ed. Canadian Society of Soil Science, CRC Press and Taylor & Francis Group. Oxford, UK.
- Kabata-Pendias, A, and and H. Pendias. 2001. Trace elements in soils and plants. 3rd ed. CRC Press, Boca Raton, Florida.
- Nicholson, F.A., S.R. Smith, B. J. Alloway, C. Carlton-Smith, and B. J. Chambers. 2006. Quantifying heavy metal inputs to agricultural soils in England and Wales. Water and Environment Journal 20(2): 87-95. Available at: http://www3.interscience.wiley.com/cgi-bin/fulltext/118593388/PDFSTART
- Sparks, D.L. (ed). 1996. Methods of Soil Analysis: chemical methods. Part 3. Soil Sci. Soc. Am. Book Series No. 5. ASA-SSSA, Madison, WI.
- Westerman, R.L. (ed) 1990. Soil Testing and Plant Analysis. 3rd edition. ASA-SSSA, Madison, WI.



